'The Amazing Spider-Man' stars Andrew Garfield and Emma Stone are masters of ... - New York Daily News

Jaimie Trueblood

Emma Stone as Gwen Stacy and Andrew Garfield as Peter Parker in 'The Amazing Spider-Man'

On-screen chemistry isn’t an exact science, even for Peter Parker.

Director Mark Webb and the producers of “The Amazing Spider-Man,” opening Tuesday, knew that all the CGI-infused fight sequences, 3-D camera tricks and heart-pounding stunts wouldn’t mean a thing if they didn’t find the perfect Peter and an equally perfect Gwen Stacy, Peter’s true love from the original 1960s Marvel comic books.

The already-risky rebooting of the successful Tobey Maguire/Kirsten Dunst franchise from 2002-2007 could have been an experiment gone awry had the casting not clicked. But it proved to be a winning formula once British stage veteran Andrew Garfield, 28, and comedy alumna Emma Stone, 23, emerged from an international casting search.

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Webb compares the way Garfield and Stone play off each other in an awkward high school hallway scene to ’50s comic duo Mike Nichols and Elaine May.

That playful, rapid-fire back-and-forth was on display when the stars of “The Amazing Spider-Man” â€" now a couple off-screen as well â€" recently sat down for an exclusive interview with the Daily News.

Daily News: So, this movie plunks Peter Parker back to his high school days. Emma, even though you were home-schooled, between this movie, “Easy A” and “Superbad,” you can’t seem to graduate, even though you’re now 23.

Emma Stone: I know, are you kidding me?! But as long as they cast me in high school, I’ll take it. There’s going to come a day when [if I passed on one of these roles] I would kick my own aâ€" later on if I was like, ‘You complained about playing younger? Really?!’ There’s nowhere to go but up.

Andrew Garfield: Because you’re looking, well, old.

Stone: I am.

Garfield: You’re looking proper old.

Stone: I am looking proper old.

Enid Alvarez/New York Daily News

DN: Andrew, did the scenes in high school give you flashbacks to your own high-school days?

Garfield: Yeah, of course. Everyone wants to relive high school and do it better â€" and I got to do it as Peter Parker, which is the most awesome thing ever.

Stone: Are you serious? If you had the chance to go back and do it again, you’d do it again?

Garfield: Yeah, of course. And you’d do it completely differently?

Stone: Hell, no. But most people say they’d never go back.

Garfield: Yeah, but you were simply at home with your mom.

Stone: Yeah, it was awesome. But I wouldn’t do it again.

Garfield: You were the coolest kid in school!